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posted by  butter cup on 3/25/2008 4:00:23 AM  |  status: Closed  

exothermic + or -

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I did a lab in which I measured the total Joules released by a reaction between HCl and NaOH.  When I combined the acid and base the temp of the solution increased.  This is an exothermic reaction right?  When I followed my worksheet I got total joules realeased by the reaction as aprox. 2400 J.  If it is an exothermic reaction do I automaticaly make it negative....you don't get a negative by way of math?  And would that make joules released per mole of water formed negative also?
 
Hope my ramblings make sense.  I've been working on this all night.
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posted by tee#1 on 3/25/2008 4:40:01 AM  |  status: Live
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butter cup's comment:
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Yes you are correct, if  your reaction caused an increase in temperature, energy was released from the system into the surrounding and is an exothermic process. I am assuming the experiment is Calorimetry....This is straight from a chem textbook:
If so ...the walls of the calorimeter are insulated  so that there is no exchange of heat with the air outside the calorimeter...it follows then that the only heat flow is between the reaction system  and the calorimeter. The heat flow for the reaction system is equal in magnitude but opposite in sign to that for the calorimeter:
 
q rxn = -q calorimeter
 
Notice that if the reaction is exothermic (q rxn < 0), q calorimeter must be positive; that is, heat flows from the reaction mixture into the calorimeter.
 
Note: the rxn mixture is the system the calorimeter is the surroundings.
hope this is helpful!
 

 

 
 
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