the reaction for the combustion of sucrose is
C12H22O11(s) + 12O2(g) -----> 12 CO2(g) + 11 H2O(l)
the standard enthalpy change for the reaction is
ΔH0rxn =ΣviHi[products] -ΣviHi[reactants]
=[12 ΔH0f(CO2(g)) +11ΔH0f( H2O(l))] -[1ΔH0f(C12H22O11(s))+12ΔH0f(O2(g))]
=[12(-393.5)+11(-285.8)]-[ΔH0f(C12H22O11(s))+12(0)]
-5639.7KJ/mol = -7865.8KJ/mol -ΔH0f(C12H22O11(s))
ΔH0f(C12H22O11(s)) = -2226.1KJ/mol