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posted by  shinina on 11/28/2008 11:19:59 AM  |  status: Live  

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Course Textbook Chapter Problem
General Chemistry N/A N/A N/A
Question Details:
BaCl2(aq) + Na2C2O4(aq) __ BaC2O4(s) + 2NaCl(aq)
 
(1)   What is the total ionic equation for this reaction ?    (2) What is the net ionic equation ? (3) Calculate the the theoretical yield in moles of barium oxalate (BaC2O4) formed if 11.00 mL of 8.25 x 10-2M of BaCl2 solution were mixed with 10.00 mL of 9.35 x 10-2 M NaC2O4 solution.  (4) calculate the molar mass of BaC2O4. (5) If a student performed the reaction  described in question   (3)     and isolated 0.1989 g of BaC2O4. How many moles of BaC2O4 did the student isolate? (6) calculate the percent yield for the student's experiment in question.(5)                                                                                 
ShiNina
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posted by Werner on 12/1/2008 7:53:09 AM  |  status: Live
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shinina's comment:
"Thanks so much!"
Response Details:
 1) the total ionic equation for the reaction  BaCl2(aq) + Na2C2O4(aq) ----------->  BaC2O4(s) + 2NaCl(aq)
       Ba2+(aq) + 2Cl-(aq) + 2Na+(aq) + C2O42-(aq) ----------> BaC2O4(s) + 2Cl-(aq) + 2Na+(aq)
   2) Net ionic equation for the reaction
      
     Ba2+(aq) +  C2O42-(aq)  ----------> BaC2O4(s)
 3) Moles of  BaCl2  = molarity * volume in liters
                                 = 0.0825 mol/L * 0.011 L
                                 = 0.0009075 mol
    Moles of NaC2O4 = molarity * volume in liters
                                 = 0.0935 mol/L * 0.01 L
                                 = 0.000935 mol
 Hence   BaCl2  is the limiting reactant
       ∴ The number of moles of BaC2O4(s)  formed = moles of  BaCl2   reacted
                                                                               = 0.0009075 mol * 225.327 g/mol
                                                                               = 0.2045 g
  the theoretical yield in moles of barium oxalate (BaC2O4) formed = 0.0009075 mol
 4) The molar mass of BaC2O4(s) = 137.327 g/mol + 2*12.0 g/mol + 4*16.0 g/mol
                                                    = 225.327 g/mol
 5) The number of moles of BaC2O4(s) isolated =  0.1989 g / 225.327 g/mol
                                                                         = 0.000883 mol
  6) the percent yield for the student's experiment  = (0.1989 g /0.2045 g)*100
                                                                            = 97.26%
 
 
 
 
  
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