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posted by  ^___^ on 11/30/2008 12:13:48 AM  |  status: Live  

PLEASE HELP: Volumetric Analysis

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Question Details:
The compound XCl2(NH3)2 can be formed by reacting XCl4 with NH3. Suppose that 3.571 g of XCl4 reacts with excess NH3 to give 3.180 g of XCl2(NH3)2. What is the element X?
    I know the answer is Pt. I just don't know how to get this answer...Please help~!
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posted by Ricky Wilkins on 12/1/2008 7:52:21 AM  |  status: Live
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"Thanks! :)"
Response Details:
 The balanced equation of the given reaction is
                    XCl4  +  2NH3  --------->   XCl2(NH3)2
 The number of moles of the XCl4 present initially = The number of moles of   XCl2(NH3)2
 Since number of moles = weight/M.Weight
 Therefore
             (Weight/M.Wt) of reactants  = (Weight/M.Wt) of products
                  Weight of reactants/Weight of Products   =  M.Wt of reactants/ M.Wt of products
                      3.571g/3.180g        = M.Wt(rea) / M.Wt(pro)
                           1.122                 =  M.Wt(rea) / M.Wt(pro)
 Therefore Molecular weight of reactants  =  1.122(M.Wt of products)
               [xg + 4(35.45g/mol for Cl) ]     = 1.122[xg+2(35.45g/mol for Cl) + 2(17g/mol for NH3)]
 By solving this equation we get the value of x,that is the molecular weight of X.
 Therefore  x = 194.36g/mol
 This is the M.Wt of the Platinum,Pt.
 Therefore un known X = Pt.
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